http://www.macosxhints.com/index.php?topic=unix - which has OS X UNIX hints.
I think http://www.osxzone.com/ has a UNIX section, but I can’t bring the site up at the moment to verify that.
You can go to the source of the POSIX specification at: http://www.opengroup.org/onlinepubs/007904975/toc.htm
I also highly recommend Unix Power Tools, Third Edition by Shelley Powers; This book covers just about everything that can be done from a UNIX command line and the third edition covers the specifics/differences for OS X as well.
The O’Reilly Mac General/DevCenter [http://www.macdevcenter.com/] has some UNIX related info. They also publish a boat-load of UNIX related books; most of which apply to Mac OS X with very little effort.
Oh, and there is always man, whatis, and apropos from the command line itself.
http://www.osxfaq.com/ - Also has a OS X UNIX section.
There’s also some short hints at http://borkware.com/quickies/one?topic=Unix
i’ve found a Mac-Unix thread here: http://www.unix.com
Apple.com > Support > Mac OS X Technologies > Unix: http://discussions.apple.com/forum.jspa?forumID=735